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Black Vigent Rock Scalps are unique materials in Xenoblade Chronicles X. They can be obtained from black Vigents, or for 138 Reward Tickets at the Network Console in the BLADE Barracks. They are components in X, XV, and XX Front Attack Plus and PositionDmg.FRONT augments.

Sources

Enemy Level Area
Volcannon Vigent 51-70 Cauldros
Vainamo, the Bellower 38 Cauldros